You can juggle with the letters, from the previous path. I would adise against it though, as you may end up with lost paths to running progams.
If it is of any satisfaction, when you reboot into Vista, it will again be C:
Operating System Windows 7 All varieties (64Bit) Now Windows 8
Computer Type Self built
CPU Type and Speed AMD X4 2.8 Ghz
Motherboard Chipset Gigabyte MA74GMT
System Memory Type 4096 MB DDR-3 1333 Mhz
Video Card Type and Speed Radeon HD 5450 1024 MB PCI-E
Hard Drive 320 GB SATA
Anti-virus Software MSE
Computer Skill Level Self-Taught Expert
Favorite Game Pool/snooker Online.